Ternary Representation of Stochastic Change and the Origin of Entropy and Its Fluctuations

February 25, 2019 Β· Declared Dead Β· πŸ› arXiv.org

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Authors Hong Qian, Yu-Chen Cheng, Lowell F. Thompson arXiv ID 1902.09536 Category cond-mat.stat-mech Cross-listed cs.IT, math-ph Citations 6 Venue arXiv.org Last Checked 2 months ago
Abstract
A change in a stochastic system has three representations: Probabilistic, statistical, and informational: (i) is based on random variable $u(Ο‰)\to\tilde{u}(Ο‰)$; this induces (ii) the probability distributions $F_u(x)\to F_{\tilde{u}}(x)$, $x\in\mathbb{R}^n$; and (iii) a change in the probability measure $\mathbb{P}\to\tilde{\mathbb{P}}$ under the same observable $u(Ο‰)$. In the informational representation a change is quantified by the Radon-Nikodym derivative $\ln\left( \frac{ d \tilde{\mathbb{P}}}{ d\mathbb{P}}(Ο‰)\right)=-\ln\left(\frac{ d F_u}{ d F_{\tilde{u}}}(x)\right)$ when $x=u(Ο‰)$. Substituting a random variable into its own density function creates a fluctuating entropy whose expectation has been given by Shannon. Informational representation of a deterministic transformation on $\mathbb{R}^n$ reveals entropic and energetic terms, and the notions of configurational entropy of Boltzmann and Gibbs, and potential of mean force of Kirkwood. Mutual information arises for correlated $u(Ο‰)$ and $\tilde{u}(Ο‰)$; and a nonequilibrium thermodynamic entropy balance equation is identified.
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